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Heterogeneous Catalysis in Organic Chemistry - Gerard V Smith, Ferenc Notheisz (AP, 1999) pdf

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 							The features of this book which will be of special interest to academic organic chemists are the introduction
(Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic
reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents
problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can
supplement advanced chemistry courses.
  
  Most synthetic organic chemists use a variety of "protecting
groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on
another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions
and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not
found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the
recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter
extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for
seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic
organic chemistry.
  
  Many academic organic chemists are not aware of recent advances in heterogeneous
enantioselective catalysis (Chapter 3) or in selective low temperature, liquid phase heterogeneous catalytic oxidations
by hydrogen peroxide (Chapter 6). These specialty topics are timely and may be new to academic organic chemists and can
be used to supplement their advanced courses.
  
  Several features of this book will also be of special
interest to industrial chemists who are unfamiliar with heterogeneous catalysis. Many good organic chemists are hire by
industry. They synthesize a new compound using standard organic synthetic techniques but are informed by their
supervisor that they must convert some of their synthetic steps into heterogeneous catalytic steps. They may not have
been exposed to heterogeneous catalysis and have few places to turn. This book offers them a crash course in
heterogeneous catalysis as well as many examples of reactions and conditions with which they can start their search.
  
  Those industrial organic chemists already familiar with heterogeneous catalysis will find this book useful
as a reference to many examples in the recent literature. They will find recent surface science discoveries correlated
with heterogeneous catalysis or organic reactions and mechanistic suggestions designed to stimulate innovative
nontraditional thinking about organic reactions on surfaces.
  
  
  Key Features
  * Written by
organic chemists for organic chemists
  * Introduces heterogeneous catalysis concepts and language
  *
Presents a comprehensive compilation of protecting group removal procedures
  * Covers liquid-phase hydrogenations,
hydrogenolysis, and oxidations
  * Addresses heterogeneous methods for producing pure enantiomers of chiral
products
  * Examines the emerging field of heterogenized homogeneous catalysts
  * Mixes practical
applications with mechanistic interpretations 						

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